01847nas a2200193 4500008004100000022001400041245005200055210005200107260001200159300001400171490000700185520124200192100002201434700002901456700002401485700001501509700001701524856011201541 2018 eng d a0091-761300aBarium and barite dynamics in Antarctic streams0 aBarium and barite dynamics in Antarctic streams c08/2018 a811 - 8140 v463 a

Most natural waters are undersaturated with respect to barite (BaSO4), and while much work has focused on the processes of microbially mediated barite precipitation in undersaturated solutions, particularly in marine environments, little documentation exists on the changes in barite saturation in stream waters. We examined ephemeral glacial meltwater streams in the McMurdo Dry Valleys, Antarctica, that undergo large variations in streamflow and temperature on both a diel and seasonal basis. We measured dissolved Ba in stream water in downstream transects and on a diel cycle, total Ba in stream sediments, algal mats, and lake sediments. Ba concentrations decreased downstream in all four transects, and mineral saturation modeling indicates these waters go from supersaturated to undersaturated with respect to barite in very short distances. Ba is concentrated in stream benthic algal mats at a factor less than observed in marine systems. Both seasonal and diel changes in stream water temperature affect the solubility of barite near glacial sources. Our work shows that both changing stream temperature and the presence of algal materials likely play significant roles in controlling Ba concentrations in polar streams.

1 aSaelens, Elsa, D.1 aGardner, Christopher, B.1 aWelch, Kathleen, A.1 aWelch, Sue1 aLyons, Berry uhttps://pubs.geoscienceworld.org/gsa/geology/article/545184/Barium-and-barite-dynamics-in-Antarctic-streams04850nas a2200217 4500008004100000022001300041245007600054210006900130260001200199300001400211490000800225520403500233100001704268700001704285700002204302700001904324700001404343700002404357700002104381856023004402 2014 eng d a0009254100aBoron isotopic geochemistry of the McMurdo Dry Valley lakes, Antarctica0 aBoron isotopic geochemistry of the McMurdo Dry Valley lakes Anta c10/2014 a152 - 1640 v3863 a

 

The geochemistry of boron was investigated in the ice-covered lakes and glacier meltwater streams within Taylor and Wright Valley of the McMurdo Dry Valleys (MCM), Antarctica, in order to achieve a greater understanding of the source of boron to these aquatic systems and how in-lake processes control boron concentration. Selected lake depths (surface and bottom water) and streams were analyzed for boron geochemistry. Boron stable isotope values in these waters span the range of + 12.3‰ to + 51.4‰, which corresponds to the variations from glacier meltwater streams to the hypolimnion of a highly evaporated hypersaline lake. The data demonstrate that the major sources of B to the aquatic system are via terrestrial chemical weathering of aluminosilicates within the stream channels, and a marine source, either currently being introduced by marine-derived aerosols or in the form of ancient seawater. Lakes Fryxell, Hoare, and upper waters of Lake Joyce, which experience more terrestrial influence of aluminosilicate chemical weathering via glacial meltwater streams, display a mixture of these two major sources, while the source of B in the bottom waters of Lake Joyce appears to be primarily of marine origin. Lakes Bonney and Vanda and the Blood Falls brine have a marine-like source whose δ11B values have become more positive by mineral precipitation and/or adsorption. Don Juan Pond displays a terrestrial aluminosilicate influence of a marine-like source. These hypersaline lake waters from Antarctica are similar in δ11B to other hypersaline lake waters globally, suggesting that similar processes control their B geochemistry.

 

 

1 aLeslie, D.L.1 aLyons, Berry1 aWarner, Nathaniel1 aVengosh, Avner1 aOlesik, J1 aWelch, Kathleen, A.1 aDeuerling, Kelly uhttp://linkinghub.elsevier.com/retrieve/pii/S000925411400391Xhttp://api.elsevier.com/content/article/PII:S000925411400391X?httpAccept=text/xmlhttp://api.elsevier.com/content/article/PII:S000925411400391X?httpAccept=text/plain00637nas a2200169 4500008004100000245009400041210006900135300001100204490000800215100002300223700002000246700002400266700002400290700002400314700001700338856011200355 2007 eng d00aThe biogeochemical evolution of cryoconite holes on glaciers in Taylor Valley, Antarctica0 abiogeochemical evolution of cryoconite holes on glaciers in Tayl aG04S350 v1131 aBagshaw, Elizabeth1 aTranter, Martyn1 aFountain, Andrew, G1 aWelch, Kathleen, A.1 aBasagic, Hassan, J.1 aLyons, Berry uhttps://mcm.lternet.edu/content/biogeochemical-evolution-cryoconite-holes-glaciers-taylor-valley-antarctica00536nas a2200157 4500008004100000245006700041210006600108300001200174490000600186100001200192700002400204700001700228700002100245700002400266856008800290 2003 eng d00aBiochemistry of Si in the McMurdo Dry Valley lakes, Antarctica0 aBiochemistry of Si in the McMurdo Dry Valley lakes Antarctica a737-7490 v11 aPugh, H1 aWelch, Kathleen, A.1 aLyons, Berry1 aPriscu, John, C.1 aMcKnight, Diane, M. uhttps://mcm.lternet.edu/content/biochemistry-si-mcmurdo-dry-valley-lakes-antarctica