02147nas a2200205   4500008004100000245009900041210006900140260005900209300000800268490000900276520148500285653001501770653001601785653001401801653001801815653001701833100002201850700002101872856004801893       2024                        eng d00aDevelopment of a laboratory simulation for freeze-thaw of aeolian sediments in glacial systems0 aDevelopment of a laboratory simulation for freezethaw of aeolian  aBoulder, CO, USAbUniversity of Colorado Boulderc2024  a2610 vM.A.3 a<p>Glacial systems are vital for supplying trace metals, nutrients, and weathering products to downstream ecosystems. While subglacial and proglacial weathering pathways are highly studied, supraglacial weathering processes receive less attention. Aeolian sediments on glaciers can lower albedo, generating meltwater; this water can refreeze around sediment grains during cloudy periods or when the sun is obstructed, resulting in a freeze-thaw process. For solute generation in the most upstream source in glacial-proglacial environments, it&#39;s unclear whether chemical or physical weathering dominates nutrient release. This study presents a methodology to simulate freeze-thaw processes in a controlled laboratory setting to understand the importance of freeze-thaw in nutrient mobilization. Analysis of sediments from Antarctica&#39;s McMurdo Dry Valleys showed significant differences in the concentrations of ion, nutrient, and trace metal between initial wetting and subsequent freeze-thaw cycles. For example, phosphorus concentrations consistently increased with each cycle, indicating that freeze-thaw is an important mobilization mechanism for this nutrient. Silicon increased from cycle 1-30 but decreased at cycle 60 and iron concentrations were initially higher but decreased during subsequent cycles. This research highlights the importance of freeze-thaw processes in understanding glacial weathering dynamics and nutrient release for downstream ecosystems.</p>10aAntarctica10afreeze-thaw10anutrients10aTaylor Valley10atrace metals1 aMondragon, Denise1 aDiaz, Melisa, A.  uhttps://www.proquest.com/docview/306679220202199nas a2200205   4500008004100000245013600041210006900177260003400246490000900280520151100289653001401800653001901814653001201833653001401845653002501859653001101884100002401895700002501919856004901944       2012                        eng d00aModeling nitrate concentrations in an Antarctic glacial meltwater stream under fluctuating hydrologic conditions and nitrate inputs0 aModeling nitrate concentrations in an Antarctic glacial meltwate  bPennsylvania State University0 vM.S.3 a<p>The McMurdo Dry Valleys comprise a unique polar desert ecosystem in Victoria Land, Antarctica. The hydrologic system in the Dry Valleys is often characterized as being simplified compared to temperate watersheds, due to the ability to identify physical boundaries and nutrient sources and sinks. We seek to characterize the evolution of streamflow, solutes, and nutrients along a glacial meltwater stream in the McMurdo Dry Valleys, and to understand the role of different sources and sinks under varying hydrologic conditions. The study presented here includes streamflow routing, solute modeling, and nitrate concentration modeling in Von Guerard stream, a stream with abundant algal coverage in the McMurdo Dry Valleys region of Antarctica. The streamflow model is a solution to the kinematic wave routing problem. Solute modeling addresses advection, dispersion, as well as hyporheic zone inputs, which are controlled by weathering and hyporheic exchange. Lastly, the nitrate model builds on the solute model with the addition of a gross primary production (GPP) component. Results indicate that the hyporheic source of nitrate is controlling due to rapid exchange with the main channel. GPP impacts are small due to light-saturated conditions for a majority of the season, but provide a consistent sink for nitrate. The role of advective and dispersive transport is highly dependent on flow conditions, with advective transport controlling at high flows and dispersive controlling at low flows.</p>10ahydrology10ahyporheic zone10anitrate10anutrients10aprimary productivity10astream1 aBernzott, Emily, D.1 aGooseff, Michael, N.  uhttps://etda.libraries.psu.edu/catalog/1531603517nas a2200349   4500008004100000245015900041210006900200260003400269490000900303520243200312653001502744653002002759653002402779653001402803653002802817653001702845653001302862653001402875653001402889653001302903653002402916653002002940653001402960653001702974653002102991653002103012653001503033653002003048100002503068700002503093856004903118       2011                        eng d00aHydrologic controls of nutrient fluxes in glacial meltwater streams at inter-annual, seasonal, and daily timescales in the McMurdo Dry Valleys, Antarctica0 aHydrologic controls of nutrient fluxes in glacial meltwater stre  bPennsylvania State University0 vM.S.3 a<p>In the McMurdo Dry Valleys of Antarctica, glaciers are hydrologically linked to closed-basin lakes at the valley floor by glacial meltwater streams. Streams flow through porous, well-defined channels with extensive chemically active hyporheic zones. Temporally varying dynamics of meltwater generation and sub-stream thaw depth are thought to control the potential for the hyporheic zone and benthic communities to influence transport of nutrients and dissolved ions downstream. Using the McMurdo LTER database, patterns in stream discharge, electrical conductivity (both with 15-minute sampling intervals), and solute chemistry (weekly sampling intervals) were examined on eight MDV streams from 1990-2008. Discharge and electrical conductivity values were highly variable among streams. Discharge values were highly dependent upon glacial source area, but meteorological and topographical complexities create large variability at all time scales. The longer streams were found to have much higher electrical conductivity values than the shorter streams, suggesting that there are more opportunities for hyporheic weathering reactions along longer stream reaches. Weekly sampled water solutes from each stream&#39;s entire record were plotted against the discharge recorded at the time when the sample was taken. Silicate concentrations displayed a decreasing logarithmic relationship, while nutrient concentrations had no apparent relationship. This suggests that with the exception to bioreactive solutes, the majority of hyporheic interactions could possibly be characterized by electrical conductivity and discharge. To attain information on in-stream nutrient dynamics and nutrient fluxes, glacial source water at the upper reach of Green Creek and stream outlet water at the lower reach of Green Creek were sampled hourly for two separate diel periods during the 2008-09 austral summer. Both dates were in late January under two distinct flow conditions (~0.5 L/s and ~10 L/s). Under low flow conditions, nutrient cycling was found to be uptake dominated. High flow conditions showed both uptake and regeneration with much higher nutrient loads, but as in the low flow conditions, no apparent temporal trends were found. Nutrient concentrations could not be predicted using the two parameters of discharge and electrical conductivity with in-stream nutrient dynamics likely too complicated at the sub-daily scale.</p>10aAntarctica10abiogeochemistry10achemical weathering10adischarge10aelectrical conductivity10aglacial melt10aglaciers10ahydrology10ahyporheic10aMCM LTER10aMcMurdo Dry Valleys10anutrient fluxes10anutrients10apolar desert10asolute chemistry10astream chemistry10astreamflow10awater chemistry1 aWeaver, Mitchell, R.1 aGooseff, Michael, N.  uhttps://etda.libraries.psu.edu/catalog/11568