<?xml version="1.0" encoding="UTF-8"?><xml><records><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Singley, Joel G.</style></author><author><style face="normal" font="default" size="100%">Salvatore, Mark R.</style></author><author><style face="normal" font="default" size="100%">Michael N. Gooseff</style></author><author><style face="normal" font="default" size="100%">Diane M. McKnight</style></author><author><style face="normal" font="default" size="100%">Eve-Lyn S. Hinckley</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Differentiating physical and biological storage of nitrogen along an intermittent Antarctic stream corridor</style></title><secondary-title><style face="normal" font="default" size="100%">Freshwater Science</style></secondary-title><short-title><style face="normal" font="default" size="100%">Freshwater Science</style></short-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">hyporheic zone</style></keyword><keyword><style  face="normal" font="default" size="100%">McMurdo LTER</style></keyword><keyword><style  face="normal" font="default" size="100%">nitrogen cycling</style></keyword><keyword><style  face="normal" font="default" size="100%">nutrient budget</style></keyword><keyword><style  face="normal" font="default" size="100%">organic matter</style></keyword><keyword><style  face="normal" font="default" size="100%">periphyton</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2023</style></year><pub-dates><date><style  face="normal" font="default" size="100%">09/2023</style></date></pub-dates></dates><urls><web-urls><url><style face="normal" font="default" size="100%">https://www.journals.uchicago.edu/doi/10.1086/725676</style></url></web-urls></urls><volume><style face="normal" font="default" size="100%">42</style></volume><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;In many temperate streams, biological uptake of N acts to attenuate the transport of excess N from allochthonous anthropogenic imports. Relatively few studies have determined how this N uptake relates to the magnitude of physical vs. biological N storage in the stream corridor, especially for intermittent systems where allochthonous N imports are often low and N transport may only occur during brief periods of streamflow. Glacial meltwater streams in the McMurdo Dry Valleys of Antarctica provide an excellent setting to quantify autochthonous N cycling and storage processes supported by abundant algal mats and well-connected hyporheic zones. We combined historic point-scale sediment and periphyton sample datasets with remote sensing-based modeling of periphyton coverage to estimate how much N was stored in periphyton biomass and the hyporheic zone of a 5-km long McMurdo Dry Valley stream corridor (&amp;gt;100,000 m&lt;sup&gt;2&lt;/sup&gt;). We contextualized these N storage calculations by estimating the magnitude of annual N imports to and exports from the stream corridor based on &amp;gt;2 decades of streamflow and surface water data, source glacier ice cores and meltwater data, and past studies of local aeolian deposition and biological N fixation rates. We found that in this highly oligotrophic system, stream corridor-scale N storage was ~1000x that of total annual N import or export fluxes. More than 90% of this temporarily stored N was autochthonous organic matter in the shallow (&amp;lt;10 cm) hyporheic zone, which acts as a reservoir that sustains N availability in the water column. Despite its location in a polar desert devoid of higher-order vegetation, area-normalized N storage (~40 g N/m&lt;sup&gt;2&lt;/sup&gt;) was greater than that reported for streams at lower latitudes (~1&amp;ndash;22 g N/m&lt;sup&gt;2&lt;/sup&gt;). We also demonstrated that NH&lt;sub&gt;4&lt;/sub&gt;&lt;sup&gt;+&lt;/sup&gt; sorption to stream sediment may be an important physicochemical N storage mechanism that responds to short-term fluctuations in streamflow and governs the mobility of inorganic N. Altogether, this research illustrates the importance of quantifying N storage within stream corridors when evaluating the significance of internal cycling and physical retention processes that modulate N availability.&lt;/p&gt;</style></abstract><issue><style face="normal" font="default" size="100%">3</style></issue></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Singley, Joel G.</style></author><author><style face="normal" font="default" size="100%">Gooseff, Michael N.</style></author><author><style face="normal" font="default" size="100%">Diane M. McKnight</style></author><author><style face="normal" font="default" size="100%">Eve-Lyn S. Hinckley</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">The role of hyporheic connectivity in determining nitrogen availability: Insights from an intermittent Antarctic stream</style></title><secondary-title><style face="normal" font="default" size="100%">Journal of Geophysical Research: Biogeosciences</style></secondary-title><short-title><style face="normal" font="default" size="100%">J Geophys Res Biogeosci</style></short-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">Antarctica</style></keyword><keyword><style  face="normal" font="default" size="100%">autochthonous nitrogen</style></keyword><keyword><style  face="normal" font="default" size="100%">hyporheic zone</style></keyword><keyword><style  face="normal" font="default" size="100%">nitrogen cycling</style></keyword><keyword><style  face="normal" font="default" size="100%">streamflow</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2021</style></year><pub-dates><date><style  face="normal" font="default" size="100%">04/2022</style></date></pub-dates></dates><urls><web-urls><url><style face="normal" font="default" size="100%">https://agupubs.onlinelibrary.wiley.com/doi/10.1029/2021JG006309</style></url></web-urls></urls><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;Due to widespread manipulation of nitrogen (N), much research has focused on processes controlling the fate of anthropogenic N in streams. Yet, in a variety of oligotrophic systems, N fixed by periphyton is a significant driver of ecosystem metabolism. Due to difficulties partitioning allochthonous and autochthonous sources, there is limited information regarding how the latter is processed. Autochthonous N may be particularly important in alpine, arid, or polar environments. We test the hypothesis that the availability of remineralized autochthonous N is controlled by connectivity between the hyporheic zone and main channel due to the contrasting biogeochemical functions of benthic autotrophs (including N‐fixing &lt;em&gt;Nostoc&lt;/em&gt;) and hyporheic heterotrophs in an intermittent Antarctic stream. There, we collected surface water and hyporheic water concurrently at 4‐6 hour intervals over a 32.5‐hr period during one flow season and opportunistically throughout a second. Hyporheic water had 7 to 30 times greater nitrate‐N concentrations relative to surface water across all flow conditions. In contrast, ammonium concentrations were generally lower, although similar among locations. Additionally, nitrate in hyporheic water was positively correlated with silica, an indicator of hyporheic residence time. A laboratory assay confirmed prior inferences that hyporheic microbial communities possess the functional potential to perform nitrification. Together, these findings suggest that remineralized autochthonous N accumulates in the hyporheic zone even as streamflow varies and likely subsidizes stream N availability&amp;mdash;which supports prior inferences from N stable isotope data at this site. These results highlight the importance of hyporheic connectivity in controlling autochthonous N cycling and availability in streams.&lt;/p&gt;</style></abstract></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>32</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Singley, Joel G.</style></author></authors><secondary-authors><author><style face="normal" font="default" size="100%">Eve-Lyn S. Hinckley</style></author><author><style face="normal" font="default" size="100%">Michael N. Gooseff</style></author></secondary-authors></contributors><titles><title><style face="normal" font="default" size="100%">Stream corridor connectivity controls on nitrogen cycling</style></title></titles><keywords><keyword><style  face="normal" font="default" size="100%">Antarctica</style></keyword><keyword><style  face="normal" font="default" size="100%">hyporheic zone</style></keyword><keyword><style  face="normal" font="default" size="100%">nitrogen cycling</style></keyword><keyword><style  face="normal" font="default" size="100%">streams</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2021</style></year><pub-dates><date><style  face="normal" font="default" size="100%">05/2021</style></date></pub-dates></dates><urls><web-urls><url><style face="normal" font="default" size="100%">https://www.proquest.com/docview/2572593127</style></url></web-urls></urls><publisher><style face="normal" font="default" size="100%">University of Colorado Boulder</style></publisher><pub-location><style face="normal" font="default" size="100%">Boulder, CO, USA</style></pub-location><volume><style face="normal" font="default" size="100%">PhD</style></volume><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;As water flows downstream, it is transported to and from environments that surround the visible stream. Along with surface water, these laterally and vertically connected environments comprise the stream corridor. Stream corridor connectivity influences many ecosystem services, including retention of excess nutrients. The subsurface area where stream water and groundwater mixes&amp;mdash;the hyporheic zone&amp;mdash;represents one of the most biogeochemically active parts of stream corridors.&lt;/p&gt;&lt;p&gt;The goal of my research is to advance understanding of how connectivity between different parts of a stream corridor controls the availability and retention of nitrogen (N), a nutrient that can limit primary productivity (low-N) and negatively impact water quality (excess N). First, I developed and applied a new machine learning method to objectively characterize the extent and variability of hyporheic exchange in terms of statistically unique functional zones using geophysical data. In applying this method to a benchmark dataset, I found that hyporheic extent does not scale uniformly with streamflow and that changes in the heterogeneity of connectivity differ over small (&amp;lt;10 m) distances. Next, I leveraged the relative simplicity of ephemeral streams of the McMurdo Dry Valleys (MDVs), Antarctica, to isolate stream corridor processes that influence the fate of N. Through intensive field sampling campaigns, I found that the hyporheic zone can be a persistent source of N even in this low nutrient environment. Next, I combined historic sample data and remote sensing analysis to estimate how much N is stored in an MDV stream corridor. My results indicate that up to 103 times more N is stored in this system than is exported each year, with most of this storage in the shallow (&amp;lt; 10 cm) hyporheic zone. Lastly, I examined 25 years of data for 10 streams to assess how stream corridor processes control concentration-discharge relationships. I found that in the absence of hillslope connectivity, stream corridor processes alone can maintain chemostasis &amp;ndash; relatively small concentration changes with large fluctuations in streamflow &amp;ndash; of both geogenic solutes and primary nutrients. My analysis also revealed that solutes subject to greater control by biological processes exhibit more variability within chemostatic relationships than weathering solutes that are only minimally influenced by biota.&lt;/p&gt;&lt;p&gt;Altogether, this research advances understanding of processes that are difficult to measure or are often overlooked in typical studies of temperate stream corridors. My findings provide insight into the surprising ways in which N is mobilized, transformed, and retained due to stream corridor connectivity in intermittent stream systems with few N inputs.&lt;/p&gt;</style></abstract><work-type><style face="normal" font="default" size="100%">Doctoral</style></work-type></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>32</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Singley, Joel G.</style></author></authors><secondary-authors><author><style face="normal" font="default" size="100%">Eve-Lyn S. Hinckley</style></author></secondary-authors></contributors><titles><title><style face="normal" font="default" size="100%">Nitrate Dynamics Under Unsteady and Intermittent Flow in an Antarctic Stream</style></title><secondary-title><style face="normal" font="default" size="100%">Environmental Studies</style></secondary-title></titles><dates><year><style  face="normal" font="default" size="100%">2017</style></year></dates><urls><web-urls><url><style face="normal" font="default" size="100%">http://search.proquest.com/openview/88a6ce6614e2a0cfc757c8fd7a887504/1?pq-origsite=gscholar&amp;cbl=18750&amp;diss=y</style></url></web-urls></urls><publisher><style face="normal" font="default" size="100%">University of Colorado at Boulder</style></publisher><volume><style face="normal" font="default" size="100%">M.S.</style></volume><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;Low order streams are a primary vector and modulator for the transport of anthropogenically derived reactive nitrogen, especially as nitrate (NO3&amp;ndash;). A large proportion of low orders streams experience short-term unsteady and intermittent flow conditions, and the prevalence of these dynamics is likely to increase due to climate change and human management. While such hydrologic variability is recognized as an important first-order control on the transport of NO3&amp;ndash;, prior reliance on manual sampling has resulted in a disparity between our understanding physical and hydrochemical dynamics at short-timescales, such that a large gap exists in our understanding of how unsteady and intermittent sub-daily discharge affects instream NO3&amp;ndash; transport patterns. To address this challenge, I used in situ sensors to collect high-frequency (i.e., 15 minute) NO3&amp;ndash; concentration and discharge data in an ephemeral, oligotrophic glacial meltwater stream in the McMurdo Dry Valleys, Antarctica. I analyzed concentration-discharge relationships using a power-law framework to identify a flow threshold that governed NO3&amp;ndash; transport dynamics. I observed relative chemostasis of NO3&amp;ndash; during large magnitude diel flood pulsing events. This suggests that biological and physical processes controlling the transport and transformation of NO3&amp;ndash;, and N more generally, are likely to exhibit spatial and temporal variability at very short timescales in response to extreme hydrologic variability. Such spatiotemporal variability in N processing dynamics has not been included in prior conceptual models of N cycling in MDV streams. As such, I propose a conceptual model in which short-term flow pulsing and cessation shift sediment redox conditions and microbial processes such that the shallow hyporheic zone temporally becomes a net source and storage zone for a spatially distributed pool of NO3&amp;ndash;. The results of this approach will inform understanding of how highly variable hydrological conditions measured at very short timescales interacts with instream biogeochemical processes to control N transport.&lt;/p&gt;</style></abstract><work-type><style face="normal" font="default" size="100%">masters</style></work-type></record></records></xml>