<?xml version="1.0" encoding="UTF-8"?><xml><records><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>5</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">W. Berry Lyons</style></author><author><style face="normal" font="default" size="100%">Leslie, Deborah L.</style></author><author><style face="normal" font="default" size="100%">Michael N. Gooseff</style></author></authors><secondary-authors><author><style face="normal" font="default" size="100%">Hunt, Allen</style></author><author><style face="normal" font="default" size="100%">Egli, Markus</style></author><author><style face="normal" font="default" size="100%">Faybishenko, Boris</style></author></secondary-authors></contributors><titles><title><style face="normal" font="default" size="100%">Chemical weathering in the McMurdo Dry Valleys, Antarctica</style></title><secondary-title><style face="normal" font="default" size="100%">Hydrogeology, Chemical Weathering, and Soil Formation</style></secondary-title><tertiary-title><style face="normal" font="default" size="100%">Geophysical Monograph Series</style></tertiary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">aluminosilicate weathering</style></keyword><keyword><style  face="normal" font="default" size="100%">CaCO3 dissolution/precipitation</style></keyword><keyword><style  face="normal" font="default" size="100%">chemical weathering</style></keyword><keyword><style  face="normal" font="default" size="100%">hyporheic zone</style></keyword><keyword><style  face="normal" font="default" size="100%">McMurdo Dry Valleys</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2021</style></year></dates><urls><web-urls><url><style face="normal" font="default" size="100%">https://agupubs.onlinelibrary.wiley.com/doi/10.1002/9781119563952.ch11</style></url></web-urls></urls><number><style face="normal" font="default" size="100%">257</style></number><publisher><style face="normal" font="default" size="100%">John Wiley &amp; Sons, Inc.</style></publisher><pub-location><style face="normal" font="default" size="100%">Hoboken, NJ</style></pub-location><pages><style face="normal" font="default" size="100%">205-216</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;While chemical weathering has not always been considered an active process in the McMurdo Dry Valleys (MDV), Antarctica, long‐term geochemical and hydrological investigations have provided an overall better understanding of chemical weathering in this polar desert environment. Liquid water on the landscape is limited to stream channels as well as shallow subsurface melt features, as there is no overland flow. Stream total suspended sediment loads are low, with the sources of sediment from stream channels, aeolian input, and/or from the surfaces of glaciers. MDV soils contain high concentrations of soluble salts with little clay material, but since absent of water, these soils are a minimal location of chemical weathering. Hyporheic zones exchange water during streamflow, and these areas control the stream geochemistry over various temporal scales. Hyporheic zones promote rapid aluminosilicate weathering by moving dilute glacial meltwater into intimate contact with sediment surfaces. Rapid weathering of the aluminosilicates in the streambed and hyporheic zones is the most plausible explanation for chemostasis observed in these streams, indicating that little to no catchment processes are necessary to explain the observed chemostasis in the MDV. Shallow subsurface waters with distinct geochemical signatures have much higher dissolved Si concentrations than the stream waters and indicate that they are responsible for enhanced aluminosilicate weathering in this polar desert environment. The dissolution of CaCO&lt;sub&gt;3&lt;/sub&gt; is also a major process in the hyporheic zones as generally the streams are unsaturated with respect to calcite. Cation‐exchange reactions are also important in the evolution from Na‐Cl brines to Ca‐Cl brines within the soil column, while authigenic CaCO&lt;sub&gt;3&lt;/sub&gt; can both dissolve and precipitate depending on the condition of the system. Recently, stream channel landscapes are changing due to the melting of buried ice, creating thermokarst and water track features, resulting in a sediment and solute influx to the stream.&lt;/p&gt;</style></abstract><section><style face="normal" font="default" size="100%">11</style></section></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>32</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Weaver, Mitchell R.</style></author><author><style face="normal" font="default" size="100%">Michael N. Gooseff</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Hydrologic controls of nutrient fluxes in glacial meltwater streams at inter-annual, seasonal, and daily timescales in the McMurdo Dry Valleys, Antarctica</style></title><secondary-title><style face="normal" font="default" size="100%">Department of Civil &amp; Environmental Engineering</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">Antarctica</style></keyword><keyword><style  face="normal" font="default" size="100%">biogeochemistry</style></keyword><keyword><style  face="normal" font="default" size="100%">chemical weathering</style></keyword><keyword><style  face="normal" font="default" size="100%">discharge</style></keyword><keyword><style  face="normal" font="default" size="100%">electrical conductivity</style></keyword><keyword><style  face="normal" font="default" size="100%">glacial melt</style></keyword><keyword><style  face="normal" font="default" size="100%">glaciers</style></keyword><keyword><style  face="normal" font="default" size="100%">hydrology</style></keyword><keyword><style  face="normal" font="default" size="100%">hyporheic</style></keyword><keyword><style  face="normal" font="default" size="100%">MCM LTER</style></keyword><keyword><style  face="normal" font="default" size="100%">McMurdo Dry Valleys</style></keyword><keyword><style  face="normal" font="default" size="100%">nutrient fluxes</style></keyword><keyword><style  face="normal" font="default" size="100%">nutrients</style></keyword><keyword><style  face="normal" font="default" size="100%">polar desert</style></keyword><keyword><style  face="normal" font="default" size="100%">solute chemistry</style></keyword><keyword><style  face="normal" font="default" size="100%">stream chemistry</style></keyword><keyword><style  face="normal" font="default" size="100%">streamflow</style></keyword><keyword><style  face="normal" font="default" size="100%">water chemistry</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2011</style></year></dates><urls><web-urls><url><style face="normal" font="default" size="100%">https://etda.libraries.psu.edu/catalog/11568</style></url></web-urls></urls><publisher><style face="normal" font="default" size="100%">Pennsylvania State University</style></publisher><volume><style face="normal" font="default" size="100%">M.S.</style></volume><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;In the McMurdo Dry Valleys of Antarctica, glaciers are hydrologically linked to closed-basin lakes at the valley floor by glacial meltwater streams. Streams flow through porous, well-defined channels with extensive chemically active hyporheic zones. Temporally varying dynamics of meltwater generation and sub-stream thaw depth are thought to control the potential for the hyporheic zone and benthic communities to influence transport of nutrients and dissolved ions downstream. Using the McMurdo LTER database, patterns in stream discharge, electrical conductivity (both with 15-minute sampling intervals), and solute chemistry (weekly sampling intervals) were examined on eight MDV streams from 1990-2008. Discharge and electrical conductivity values were highly variable among streams. Discharge values were highly dependent upon glacial source area, but meteorological and topographical complexities create large variability at all time scales. The longer streams were found to have much higher electrical conductivity values than the shorter streams, suggesting that there are more opportunities for hyporheic weathering reactions along longer stream reaches. Weekly sampled water solutes from each stream&amp;#39;s entire record were plotted against the discharge recorded at the time when the sample was taken. Silicate concentrations displayed a decreasing logarithmic relationship, while nutrient concentrations had no apparent relationship. This suggests that with the exception to bioreactive solutes, the majority of hyporheic interactions could possibly be characterized by electrical conductivity and discharge. To attain information on in-stream nutrient dynamics and nutrient fluxes, glacial source water at the upper reach of Green Creek and stream outlet water at the lower reach of Green Creek were sampled hourly for two separate diel periods during the 2008-09 austral summer. Both dates were in late January under two distinct flow conditions (~0.5 L/s and ~10 L/s). Under low flow conditions, nutrient cycling was found to be uptake dominated. High flow conditions showed both uptake and regeneration with much higher nutrient loads, but as in the low flow conditions, no apparent temporal trends were found. Nutrient concentrations could not be predicted using the two parameters of discharge and electrical conductivity with in-stream nutrient dynamics likely too complicated at the sub-daily scale.&lt;/p&gt;</style></abstract><work-type><style face="normal" font="default" size="100%">masters</style></work-type></record></records></xml>