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  <dataset>
    <shortName>glac_chem_snowpit</shortName>
    <title>Snowpit chemistry from Canada, Commonwealth, and Rhone Glaciers, McMurdo Dry Valleys, Antarctica during the 2000-2001 austral summer</title>
    <creator>
      <individualName>
        <givenName>Anna</givenName>
        <surName>Bergstrom</surName>
      </individualName>
      <electronicMailAddress>annabergstrom@boisestate.edu</electronicMailAddress>
      <userId directory="https://orcid.org">https://orcid.org/0000-0002-9684-4018</userId>
    </creator>
    <creator>
      <individualName>
        <givenName>Kathleen</givenName>
        <surName>Welch</surName>
      </individualName>
      <electronicMailAddress>kathleen.welch@colorado.edu</electronicMailAddress>
      <userId directory="https://orcid.org">https://orcid.org/0000-0003-1028-3086</userId>
    </creator>
    <creator>
      <individualName>
        <givenName>W. Berry</givenName>
        <surName>Lyons</surName>
      </individualName>
      <address>
        <deliveryPoint>275 Mendenhall Lab</deliveryPoint>
        <city>Columbus</city>
        <administrativeArea>OH</administrativeArea>
        <postalCode>43210</postalCode>
        <country>US</country>
      </address>
      <phone phonetype="voice">(614) 688-3241</phone>
      <electronicMailAddress>lyons.142@osu.edu</electronicMailAddress>
      <onlineUrl>http://research.bpcrc.osu.edu/EnvironmentalGeochemistry/</onlineUrl>
      <userId directory="https://orcid.org">https://orcid.org/0000-0002-3143-7251</userId>
    </creator>
    <creator>
      <individualName>
        <givenName>Michael</givenName>
        <surName>Gooseff</surName>
      </individualName>
      <electronicMailAddress>michael.gooseff@colorado.edu</electronicMailAddress>
      <onlineUrl>http://goosefflab.weebly.com</onlineUrl>
      <userId directory="https://orcid.org">https://orcid.org/0000-0003-4322-8315</userId>
    </creator>
    <metadataProvider>
      <organizationName>McMurdo Dry Valleys LTER</organizationName>
      <onlineUrl>http://mcmlter.org/</onlineUrl>
    </metadataProvider>
    <associatedParty>
      <individualName>
        <givenName>Thomas</givenName>
        <surName>Nylen</surName>
      </individualName>
      <electronicMailAddress>thomasnylen@gmail.com</electronicMailAddress>
      <userId directory="https://orcid.org">https://orcid.org/0000-0001-9579-8702</userId>
      <role>field crew</role>
    </associatedParty>
    <associatedParty>
      <individualName>
        <givenName>Whitney</givenName>
        <surName>Gann</surName>
      </individualName>
      <role>field crew</role>
    </associatedParty>
    <associatedParty>
      <individualName>
        <givenName>Renée</givenName>
        <surName>Brown</surName>
      </individualName>
      <electronicMailAddress>rfbrown@unm.edu</electronicMailAddress>
      <userId directory="https://orcid.org">https://orcid.org/0000-0002-4986-7663</userId>
      <role>data manager</role>
    </associatedParty>
    <pubDate>2022-10-12</pubDate>
    <language>English</language>
    <abstract>
      <section>
        <para>
          <literalLayout>To examine temporal and spatial variability in snow chemistry during the 2000-2001 austral summer,&#160;snow samples were collected from the accumulation zones of Canada, Commonwealth, and Rhone Glaciers, located in Taylor Valley in the McMurdo Dry Valleys region of Antarctica. Snowpits were excavated to a depth of 2 meters at each location and samples were collected using a depth interval of 3 cm utilizing clean sampling techniques. Snow density was measured in the field at the time of sample collection. Samples were analyzed for major ions in the Crary Lab at McMurdo Station.&#160;</literalLayout>
        </para>
      </section>
    </abstract>
    <keywordSet>
      <keyword>anions</keyword>
      <keyword>calcium</keyword>
      <keyword>cations</keyword>
      <keyword>chemistry</keyword>
      <keyword>chloride</keyword>
      <keyword>ions</keyword>
      <keyword>magnesium</keyword>
      <keyword>nitrate</keyword>
      <keyword>potassium</keyword>
      <keyword>snow</keyword>
      <keyword>sodium</keyword>
      <keyword>sulfate</keyword>
      <keyword>water chemistry</keyword>
      <keywordThesaurus>LTER Controlled Vocabulary</keywordThesaurus>
    </keywordSet>
    <keywordSet>
      <keyword>anions</keyword>
      <keyword>Antarctica</keyword>
      <keyword>cations</keyword>
      <keyword>chemistry</keyword>
      <keyword>glacier</keyword>
      <keyword>ions</keyword>
      <keyword>LTER</keyword>
      <keyword>major anions</keyword>
      <keyword>major cations</keyword>
      <keyword>McMurdo Dry Valleys</keyword>
      <keyword>nitrate</keyword>
      <keyword>snow</keyword>
      <keyword>snow density</keyword>
      <keyword>Taylor Valley</keyword>
      <keywordThesaurus>Station Keywords</keywordThesaurus>
    </keywordSet>
    <keywordSet>
      <keyword>inorganic nutrients</keyword>
      <keywordThesaurus>LTER Core Areas</keywordThesaurus>
    </keywordSet>
    <additionalInfo>
      <para>
        <literalLayout>This work was funded by several grants from the U.S. National Science Foundation for Long Term Ecological Research, most recently under&#160;award #OPP-1637708.</literalLayout>
      </para>
    </additionalInfo>
    <intellectualRights>
      <section>
        <title>Data Policies</title>
        <para>
          <literalLayout>This data package is released under the Creative Commons Attribution 4.0 International License (CC BY 4.0; http://creativecommons.org/licenses/by/4.0/), which allows consumers (hereinafter referred to as “Data Users”) to freely reuse, redistribute, transform, or build on this work (even commercially) so long as appropriate credit is provided. Accordingly, Data Users are required to properly cite this data package in any publications or in the metadata of any derived products that result from its use (in whole or in part). A recommended citation is provided on the summary metadata page associated with this data package in the McMurdo Dry Valleys LTER Data Catalog (https://mcmlter.org/data), and a generic citation may be found on the summary metadata page in the repository where this data package was obtained. When these data contribute significantly to the contents of a publication, Data Users must also acknowledge that data were provided by the NSF-supported McMurdo Dry Valleys Long Term Ecological Research program (OPP-2224760). This data package has been released in the spirit of open scientific collaboration. Hence, Data Users are strongly encouraged to consider consultation, collaboration, and/or co-authorship (as appropriate) with the data package creator(s). Data Users should be aware these data may be actively used by others for ongoing research; thus, coordination may be necessary to prevent duplicate publication. Data Users should also recognize that misinterpretation of data may occur if they are used outside the context of the original study. Hence, Data Users are urged to contact the data package creator(s) if they have any questions regarding methodology or results. While substantial efforts are made to ensure the accuracy of this data package (with all its components), complete accuracy cannot be guaranteed. Periodic updates to this data package may occur, and it is the responsibility of Data Users to check for new versions. This data package is made available “as is” and comes with no warranty of accuracy or fitness for use. The creator(s) of this data package and the repository where these data were obtained shall not be liable for any damages resulting from misinterpretation, use, or misuse of these data. Finally, as a professional courtesy, we kindly request Data Users notify the primary contact referenced in the metadata when these data are used in the production of any derivative work or publication. Notification should include an explanation of how the data were used, along with a digital copy of the derived product(s). Thank you.</literalLayout>
        </para>
      </section>
    </intellectualRights>
    <distribution>
      <online>
        <url function="information">https://mcm.lternet.edu/content/snowpit-chemistry-canada-commonwealth-and-rhone-glaciers-mcmurdo-dry-valleys-antarctica</url>
      </online>
    </distribution>
    <coverage>
      <geographicCoverage>
        <geographicDescription>Snowpit was excavated in the accumulation zone of the Canada Glacier during the 2000-2001 austral summer. GPS coordinates were not obtained at the time of sample collection. Location is approximated based on the recollection of Thomas Nylen, and provided by Kathy Welch in October 2022.</geographicDescription>
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          <eastBoundingCoordinate>162.736642000000</eastBoundingCoordinate>
          <northBoundingCoordinate>-77.585997000000</northBoundingCoordinate>
          <southBoundingCoordinate>-77.585997000000</southBoundingCoordinate>
        </boundingCoordinates>
      </geographicCoverage>
      <geographicCoverage>
        <geographicDescription>Snowpit was excavated in the accumulation zone of the Commonwealth Glacier during the 2000-2001 austral summer. GPS coordinates were not obtained at the time of sample collection. Location is approximated based on the recollection of Thomas Nylen, and provided by Kathy Welch in October 2022.&#160;</geographicDescription>
        <boundingCoordinates>
          <westBoundingCoordinate>163.042805000000</westBoundingCoordinate>
          <eastBoundingCoordinate>163.042805000000</eastBoundingCoordinate>
          <northBoundingCoordinate>-77.544556310000</northBoundingCoordinate>
          <southBoundingCoordinate>-77.544556310000</southBoundingCoordinate>
        </boundingCoordinates>
      </geographicCoverage>
      <geographicCoverage>
        <geographicDescription>Snowpit was excavated in the accumulation zone of the Rhone Glacier during the 2000-2001 austral summer. GPS coordinates were not obtained at the time of sample collection. Location is approximated based on the recollection of Thomas Nylen, and provided by Kathy Welch in October 2022.</geographicDescription>
        <boundingCoordinates>
          <westBoundingCoordinate>161.968797000000</westBoundingCoordinate>
          <eastBoundingCoordinate>161.968797000000</eastBoundingCoordinate>
          <northBoundingCoordinate>-77.642947000000</northBoundingCoordinate>
          <southBoundingCoordinate>-77.642947000000</southBoundingCoordinate>
        </boundingCoordinates>
      </geographicCoverage>
      <temporalCoverage>
        <rangeOfDates>
          <beginDate>
            <calendarDate>2000-12-01</calendarDate>
          </beginDate>
          <endDate>
            <calendarDate>2001-01-20</calendarDate>
          </endDate>
        </rangeOfDates>
      </temporalCoverage>
    </coverage>
    <contact>
      <individualName>
        <givenName>McMurdo Dry Valleys LTER</givenName>
        <surName>Information Manager</surName>
      </individualName>
      <electronicMailAddress>im@mcmlter.org</electronicMailAddress>
    </contact>
    <publisher>
      <organizationName>McMurdo Dry Valleys LTER</organizationName>
      <onlineUrl>http://mcmlter.org/</onlineUrl>
    </publisher>
    <pubPlace>McMurdo Dry Valleys LTER</pubPlace>
    <methods>
      <methodStep>
        <description>
          <section>
            <para>
              <literalLayout>Samples were collected from 2 meter snowpits in the accumulation zone of Canada, Commonwealth, and Rhone Glaciers in Taylor Valley, located in the McMurdo Dry Valleys region of Antarctica.Snowpits were excavated to a depth of 2 meters at each location and samples were collected using a depth interval of approximately 3 cm utilizing clean sampling techniques. After excavation, the vertical surface was scraped in intervals to reveal a freshly exposed surface. Researchers wore non-particulating suits, clean polyethylene gloves, and used a plexiglass tray to collect the snow from a horizontal layer. Snow samples were transferred to wide-mouth Nalgene polycarbonate jars.Before analysis, the samples were melted and transferred to 60 ml plastic bottles that had been cleaned with ultrapure water. The melted snow samples were stored at ~4 &amp;deg;C until analysis in the Crary Lab at McMurdo Station using methods outlined in Welch et al. 2010 (doi: 10.1017/S0954102010000702). In order to improve the detection limit for these low concentration samples, a 350 &amp;micro;l sample loop was used to inject a larger sample volume onto the chromatography columns. The samples were analyzed between 01/21/2001 and 02/11/2001.Snow density was also measured in the field using a snow density kit obtained from the Berg Field Center, McMurdo Station, Antarctica.Timeframe and geographic coordinates of sample collections were approximated based on the recollections of Kathy Welch and Thomas Nylen.</literalLayout>
            </para>
          </section>
        </description>
      </methodStep>
    </methods>
    <dataTable>
      <entityName>GLAC_CHEM_SNOWPIT</entityName>
      <entityDescription>Glacier snowpit chemistry data.</entityDescription>
      <physical>
        <objectName>mcmlter-glac-bergstrom-chem-snowpit-20221012.csv</objectName>
        <size>17392</size>
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        <distribution>
          <online>
            <url>https://mcm.lternet.edu/sites/default/files/data/mcmlter-glac-bergstrom-chem-snowpit-20221012_0.csv</url>
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        </distribution>
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      <attributeList>
        <attribute>
          <attributeName>dataset_code</attributeName>
          <attributeLabel>Dataset code</attributeLabel>
          <attributeDefinition>Internal dataset code.</attributeDefinition>
          <storageType>string</storageType>
          <measurementScale>
            <nominal>
              <nonNumericDomain>
                <textDomain>
                  <definition>Internal dataset code.</definition>
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        <attribute>
          <attributeName>glacier</attributeName>
          <attributeLabel>Glacier</attributeLabel>
          <attributeDefinition>Name of the glacier where the sample was collected.</attributeDefinition>
          <storageType>string</storageType>
          <measurementScale>
            <nominal>
              <nonNumericDomain>
                <textDomain>
                  <definition>Name of the glacier where the sample was collected.</definition>
                </textDomain>
              </nonNumericDomain>
            </nominal>
          </measurementScale>
        </attribute>
        <attribute>
          <attributeName>sample_name</attributeName>
          <attributeLabel>Sample Name</attributeLabel>
          <attributeDefinition>Field sample identifier, which is the abbreviated glacier name and sample top depth.</attributeDefinition>
          <storageType>string</storageType>
          <measurementScale>
            <nominal>
              <nonNumericDomain>
                <textDomain>
                  <definition>Field sample identifier, which is the abbreviated glacier name and sample top depth.</definition>
                </textDomain>
              </nonNumericDomain>
            </nominal>
          </measurementScale>
        </attribute>
        <attribute>
          <attributeName>sample_depth_cm</attributeName>
          <attributeLabel>Sample Depth</attributeLabel>
          <attributeDefinition>Top depth of sample layer measured from snowpit surface.</attributeDefinition>
          <measurementScale>
            <ratio>
              <unit>
                <standardUnit>centimeter</standardUnit>
              </unit>
              <numericDomain>
                <numberType>real</numberType>
              </numericDomain>
            </ratio>
          </measurementScale>
        </attribute>
        <attribute>
          <attributeName>cl_mg_l</attributeName>
          <attributeLabel>Chloride concentration</attributeLabel>
          <attributeDefinition>Chloride concentration measured in milligrams per liter.</attributeDefinition>
          <measurementScale>
            <ratio>
              <unit>
                <standardUnit>milligramsPerLiter</standardUnit>
              </unit>
              <numericDomain>
                <numberType>real</numberType>
              </numericDomain>
            </ratio>
          </measurementScale>
        </attribute>
        <attribute>
          <attributeName>no3n_mg_l</attributeName>
          <attributeLabel>Nitrate concentration</attributeLabel>
          <attributeDefinition>Nitrate concentration measured as milligrams per liter of N.</attributeDefinition>
          <measurementScale>
            <ratio>
              <unit>
                <standardUnit>milligramsPerLiter</standardUnit>
              </unit>
              <numericDomain>
                <numberType>real</numberType>
              </numericDomain>
            </ratio>
          </measurementScale>
        </attribute>
        <attribute>
          <attributeName>so4_mg_l</attributeName>
          <attributeLabel>Sulfate concentration</attributeLabel>
          <attributeDefinition>Sulfate concentration measured as milligrams per liter of SO4.</attributeDefinition>
          <measurementScale>
            <ratio>
              <unit>
                <standardUnit>milligramsPerLiter</standardUnit>
              </unit>
              <numericDomain>
                <numberType>real</numberType>
              </numericDomain>
            </ratio>
          </measurementScale>
        </attribute>
        <attribute>
          <attributeName>na_mg_l</attributeName>
          <attributeLabel>Sodium concentration</attributeLabel>
          <attributeDefinition>Sodium concentration measured as milligrams per liter.</attributeDefinition>
          <measurementScale>
            <ratio>
              <unit>
                <standardUnit>milligramsPerLiter</standardUnit>
              </unit>
              <numericDomain>
                <numberType>real</numberType>
              </numericDomain>
            </ratio>
          </measurementScale>
        </attribute>
        <attribute>
          <attributeName>k_mg_l</attributeName>
          <attributeLabel>Potassium concentration</attributeLabel>
          <attributeDefinition>Potassium concentration measured as milligrams per liter.</attributeDefinition>
          <measurementScale>
            <ratio>
              <unit>
                <standardUnit>milligramsPerLiter</standardUnit>
              </unit>
              <numericDomain>
                <numberType>real</numberType>
              </numericDomain>
            </ratio>
          </measurementScale>
        </attribute>
        <attribute>
          <attributeName>mg_mg_l</attributeName>
          <attributeLabel>Magnesium concentration</attributeLabel>
          <attributeDefinition>Magnesium concentration measured as milligrams per liter.</attributeDefinition>
          <measurementScale>
            <ratio>
              <unit>
                <standardUnit>milligramsPerLiter</standardUnit>
              </unit>
              <numericDomain>
                <numberType>real</numberType>
              </numericDomain>
            </ratio>
          </measurementScale>
        </attribute>
        <attribute>
          <attributeName>ca_mg_l</attributeName>
          <attributeLabel>Calcium concentration</attributeLabel>
          <attributeDefinition>Calcium concentration measured as milligrams per liter.</attributeDefinition>
          <measurementScale>
            <ratio>
              <unit>
                <standardUnit>milligramsPerLiter</standardUnit>
              </unit>
              <numericDomain>
                <numberType>real</numberType>
              </numericDomain>
            </ratio>
          </measurementScale>
        </attribute>
        <attribute>
          <attributeName>comments</attributeName>
          <attributeLabel>Comments</attributeLabel>
          <attributeDefinition>Comments about the sample or analysis, if any.</attributeDefinition>
          <storageType>string</storageType>
          <measurementScale>
            <nominal>
              <nonNumericDomain>
                <textDomain>
                  <definition>Comments about the sample or analysis, if any.</definition>
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          </measurementScale>
        </attribute>
        <attribute>
          <attributeName>snowdensity_depth_cm</attributeName>
          <attributeLabel>Snow Density Sample Depth</attributeLabel>
          <attributeDefinition>Depth range of snow layer sampled for density based on visual characteristics.</attributeDefinition>
          <storageType>string</storageType>
          <measurementScale>
            <nominal>
              <nonNumericDomain>
                <textDomain>
                  <definition>Depth range of snow layer sampled for density based on visual characteristics.</definition>
                </textDomain>
              </nonNumericDomain>
            </nominal>
          </measurementScale>
        </attribute>
        <attribute>
          <attributeName>snowdensity_g_cm3</attributeName>
          <attributeLabel>Snow Density</attributeLabel>
          <attributeDefinition>Snow density measured as grams per cubic centimeter.</attributeDefinition>
          <measurementScale>
            <ratio>
              <unit>
                <customUnit>gramsPerCentimeterCubed</customUnit>
              </unit>
              <numericDomain>
                <numberType>real</numberType>
              </numericDomain>
            </ratio>
          </measurementScale>
        </attribute>
      </attributeList>
    </dataTable>
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