As part of the Long Term Ecological Research (LTER) project in the McMurdo Dry Valleys of Antarctica, a systematic aqueous geochemical sampling program has been undertaken. A series of terrestrial water samples have been collected and analyzed for major ion chemistry by ion chromatography. The concentrations of ions cover a wide range of total dissolved solids from the stream waters. This dataset shows concentrations of lithium, sodium, potassium, magnesium, calcium, iron, chlorine, bromine, silicon, fluorine, sulfate, and hydrogen ions found in various streams of the McMurdo Dry Valleys.